Phase Diagrams 
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· Because of the small dimensions of the connections in an MOS-structure, current densities are very high and the electron flux can enhance atomic diffusion.
· For the Al-Cu alloy, copper atoms are moved towards the anode by the electron flux. Copper transport is along grain boundaries and interfaces, the lowest energy paths.
· As copper atoms are depleated from the alloy, the aluminum atoms begin to move creating voids in the connection and "extruding" aluminum into the passivating SiO2.
·  These processes cause premature device failure.
From: J. M. Harper, IBM Microelectronics (2000)

 

last modified: 6/20/2001 9:16:28 AM