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Martin F. Semmelhack 361 Frick Laboratory
Princeton, NJ 08544 Lab #: 303
Office: 609-258-5501
Lab #1: 609-258-6164
Lab #2: 609-258-6165
Email
mfshack@princeton.edu
Updated 3/12/07
Chrissy Carroll
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Theses Prepared Under
Martin F. Semmelhack
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R.J.
DeFranco, Synthesis, Kinetic Acidity, and Thermal Rearrangements of
Spiro[2.3]hex-1,4-dienes and Spiro[2.3]hex-4-enes," Ph.D. Thesis,
Cornell, 1972.
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P.M.
Helquist, "Applications of Zerovalent Nickel Complexes in Synthetic
Organic Chemistry," Ph.D. Thesis, Cornell, 1973.
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George Heinsohn, "Reductive Cleavage of b-Haloethyl Protecting Groups by Chemical and Electrolytic Techniques," Ph.D. Thesis, Cornell, 1974.
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Thomas
Rogerson, "I. Reactions of 2-Ethoxy-6,7-dihydro-5(H)-azepine. II.
Methyl N-Phenylacetimidate - A New Alkylating Agent. III. Improved
Total Synthesis of Cephalotaxine," Ph.D. Thesis, Cornell, 1974.
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Joseph S. Foos, "Synthesis and Reactivity of Spirononapolyenes," Ph.D. Thesis, Cornell, 1974.
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Laurine
Ryono, "Formation of Carbon-Carbon Bonds Using Sigma-Bonded
Organometallic Reagents," Ph.D. Thesis, Cornell, 1975.
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Thomas
M. Bargar, "New Methods of Carbon-Carbon Bond Formation via
Nucleophilic Aromatic Substitution," Ph.D. Thesis, Cornell, 1977.
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Glenn
R. Clark, "Nucleophilic Aromatic Substitution Using Carbanions and
Arenetricarbonyl-Chromium Complexes," Ph.D. Thesis, Cornell, 1977.
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Harold N. Weller, "Thermal Rearrangements of the Spiro[4.4]nona-polyenes," Ph.D. Thesis Cornell, 1978.
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Clyde
S. Hutchins, "A Synthetic Approach to the Antileukemic
Bisbenzocyclooctadiene Ligand Steganone," Ph.D. Thesis, Cornell, 1979.
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Susan D. Boettger, "Approach to the Synthesis of Fomannosin," Ph.D. Thesis, Cornell, 1979.
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John J. Bisaha, "Metalation and Cyclization of Arenetricarbonylchromium Complexes," Ph.D. Thesis, Cornell, 1980.
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Steven M. Bricker, "Nickel Promoted Synthesis of Sesquiterpene a-Methylene-g-lactones," Ph.D. Thesis, Cornell, 1980. Back to the Top
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J.L. Garcia, "Selectivity in the Addition of Nucleophiles to h6-(Arene)-chromium Tricarbonyl(O) Complexes," Ph.D. Thesis, Princeton, 1982.
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Arie
Zask, "Synthesis of the Isochromanone Antibiotic Frenolicin via
Arene-Chromium and Alkene-Palladium Complexes," Ph.D. Thesis,
Princeton, 1982.
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James
W. Herndon, "Coupling of Carbon Anions with
(1,3-Diene)tri-carbonyliron(O) Complexes: Application to Organic
Synthesis," Ph.D. Thesis, Princeton, 1983.
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Christina C. Bodurow, "Ring-forming Reactions with Palladium," Ph.D. Thesis, Princeton, 1984.
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Christopher R. Schmid, "Nitroxyl-Mediated Oxidation of Alcohols and Amines," Ph.D. Thesis, Princeton, 1985.
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Hanh T. M. Le, "Regio-Selectivity in Nucleophilic Addition to Diene-Iron Complexes," Ph.D. Thesis, Princeton, 1985.
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Wayne
F. K. Schnatter, "Coupling of Iron(O) Carbene Complexes with Alkenes
and Alkynes," Ph.D. Thesis, Princeton, 1986.
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Nakcheol Jeong, "Carbene-Chromium Complexes in the Synthesis of Nogalarol," Ph.D. Thesis, Princeton, 1987.
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Ming Chang P. Yeh, "Coupling of (h1, h2-But-3-en-1-yl) Tricarbonyliron(0) and (h3-Allyl) Tricarbonyliron(0) Anion Complexes with Electrophiles," Ph.D. Thesis, Princeton, 1987.
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Edward J. Fewkes, Jr., "New Reactions and Applications of (h3-1,3-Diene) Tricarbonyliron(0) Complexes," Ph.D. Thesis, Princeton, 1987.
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Jaiwook
Park, "Reactions of Carbene Iron(0) Complexes with Organic Multiple
Bonds," Ph.D. Thesis, Princeton, 1988.
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Terry
E. Singleton, "I. Iron-Arene Cations: Nucleophilic Addition, Oxidation,
and Protonation Studies. II. Indole-Chromium Complexes: Studies toward
Synthetic Applications," Ph.D. Thesis, Princeton, 1988.
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Jae Chan Park, "(h6Quinoline) and (h6Isoquinoline) Chromium(0) Complexes: Synthesis and Reactivity," Ph.D. Thesis, Princeton, 1988.
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Nan
Zhang, "Approach to Total Synthesis of Granaticin; Stereoselective
Synthesis of Tetrahydrofurans and the Application to Synthesis of
Tetronomycin," Ph.D. Thesis, Princeton, 1990.
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Andrew David Fortney, "Substitution of Chlorobutadiene Iron Complexes," Ph.D. Thesis, Princeton, 1990.
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Daniel
Edward Ryan, "Synthetic Approaches Toward a Model for Long-Range
Electron Transfer: Preparation of a Novel U-Shaped Spacer," Ph.D.
Thesis, Princeton, 1991.
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Daniel
H. Cohen, "I. The Metal Carbonyl Promoted Rearrangement of
Arylcyclopropenes; II. Approaches Towards a Model System of Dynemicin
A," Ph.D. Thesis, Princeton, 1992.
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Hakjune
Rhee, "Indole Chromium Complexes: Synthesis of (-)-Indolactam V and
Teleocidin A," Ph.D. Thesis, Princeton, 1992.
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Chung
Ryeol Kim, "Controlled beta-Hydride Elimination During Tetrahydropyran
Ring Formation wuith Palladium(II) and Its Application to the Total
Synthesis of Tetronmycin," Ph.D. Thesis, Princeton, 1992.
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James
J. Gallagher, "Enediyne Model Studies: Synthesis Methodology, and
enol-to-Keto Actuating Mechanism, and enediyne-Netropsin
'conjujgates'," Ph.D. Thesis, Princeton, 1995.
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Yansong
Gu, "1. Synthetic Studies on GTetronomycin A; 2. A new Framework for
the Enediyne Toxins," Ph.D. Thesis, Princeton, 1995.
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Laura
Tucker Bald, "1. Studies of Metal Catalyzed Aromatic Substitution. 2.
Ring Forming Reactions of Palladium," Ph.D. Thesis, Princeton, 1995
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Yansong Gu, "1. Synthetic Studies on Tetronomycin A. 2. A New Framework for Enediyne Toxins." Ph.D. Thesis, Princeton, 1995.
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Ulrich Andres Linderschmidt, "Transition Metals in Organic Synthesis," Ph.D. Thesis, Princeton, 1999.
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Richmond
Sarpong, "A study of Enediyne Functional Analogs: Model Frameworks
Based on Calicheamicin and Esperamicin." Ph.D. Thesis, Princeton, 2000.
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Yu Jiang, “Synthetic Study of C-1027-CHR.” Ph. D. Thesis, Princeton, 2002.
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Anatoliy Chlenov, “Arene Exchange Accelerated by a Pendant Ligand.” PhD Thesis, Princeton University, 2003.
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Richard
J. Hooley, “Palladium-Catalyzed Reactions and Their Application to the
Toptal Synthesis of Plakortone B and analogs.” PhD Thesis, Princeton
University, 2004.
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