9,18-Diphenyltetrabenz[a,c,h,j]anthracene
Although this compound is a polycyclic aromatic hydrocarbon, severe
intramolecular steric interactions force the anthracene nucleus to be
greatly distorted from planarity, with an end-to-end twist of 66
degrees. Even so, this compound is perfectly stable under ordinary
conditions. For a brief communication describing its synthesis, X-ray
crystal structure, and physical properties, see
"9,18-Diphenyltetrabenz[a,c,h,j]anthracene: A Remarkably Twisted
Polycyclic Aromatic Hydrocarbon." R. A. Pascal, Jr., W. D. McMillan,
and D. Van Engen, J. Am. Chem. Soc. 1986, 108
5652-5653.
![](images/twistoflex.jpg)