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The Thermodynamics of Point Defects � Point defects increase both the enthalpy and entropy of a crystal lattice. � Thermodynamic equilibrium at constant temperature and pressure requires the Gibbs function of the system to be a minimum. � The Gibbs function, G, is given by: G = H - TS = U + PV - TS
� In an arbitrary process the Gibbs function will change such that :
� With T and P constant: dG = (dU + PdV) - TdS = dH - TdS � Both the Enthalpy and Entropy change as point defects are created by thermal energy fluctuations in the crystal lattice. |