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Leonardo da Vinci was one of the first people to formalize observations on friction. In his Codex Atlanticus and Codex Arundel he shows sketches of friction experiments. In (a), horizontal and inclined planes are used to investigate the sliding of a block under the action of gravitational, tractive and friction forces, and (b) illustrates an experiment that showed that the friction force between the plane and the block is independent of their nominal contact area.

From these experiments Leonardo concluded that: i) the friction was doubled if the weight of the object was doubled, and ii) the friction force due to a given weight was independent of the contact area between the body and the plane. He also introduced the concept of a "coefficient of friction" as the ratio between the friction force and the normal load, viz.
m = (F/W).
The measurements suggested that the coefficient of friction was constant for all bodies and equal to 0.25, i.e. the friction force was one quarter of the weight of the body. Although this is not universally correct, it is a reasonable value for many of the materials used in the tests.

Unfortunately, da Vinci's work on friction was largely undiscovered until the 1960's and the "Laws" based on these observations are associated with Amontons and Coulomb.

From: Dowson, "History of Tribology," Longman (1979)