Flame Combustion: Excess Air

If there is more air present than required to provide the stoichiometric quantity of oxygen, some oxygen will be unchanged by the combustion process and there will be additional nitrogen in the reactants and products. For 10% excess air (110% theoretical air) the methane reaction will be:

C H4 + 2.20 O2 + 2.20(3.76 N2 ) Þ C O2 + 2 H2 O + 0.20 O2 + 2.20(3.76 N2 ) + Q

If there is less oxygen present than required for complete combustion then both CO and CO2 will be present in the products as indicated below:

CH4 + x O2 + x(3.76 N2)
Þ a CO2 + b CO + 2 H2O + x(3.76 N2) + Q'

where a, b provide the balance for the carbon and oxygen equations.