Reaction Order:
The reaction order is the power to which the concentration of a reagent in the rate law is raised to. This is an experimentally determined number. For our reaction
(rxn
1)
the rate can also be expressed as
(eqn
12)
where k is the rate constant. Now taking the log of both sides of this equation we get
(eqn
13)
For runs 1, 2, and 3 the [I-] is constant. A plot of the log rate for these reactions vs log [S2O82-] is a straight line with the slope =n.
And for runs 1, 4, and 5 the [S2O82-] is held constant. A plot of the log rate for these reactions vs log [I-] also will yield a straight line with the slope =m.
For both of these graphs the slope will be a whole number, like 1 or 2 or 3... The overall rate of the reaction is m+n.
Following these basic guidelines for plotting your data:
You do not have to do an uncertainty analysis for these graphs.