9,10,11,12,13,14,15,16-Octaphenyldibenzo[a,c]naphthacene
This is an end-on view of the core of
9,10,11,12,13,14,15,16-octaphenyldibenzo[a,c]naphthacene, the most highly
twisted polycyclic aromatic hydrocarbon ever prepared. The X-ray structure
shows an end-to-end twist of 105 degrees! For a brief communication describing
the synthesis and structure of this molecule, see "An Extraordinarily Twisted
Polycyclic Aromatic Hydrocarbon," X. Qiao, D. M. Ho, and R. A. Pascal, Jr.,
Angewandte Chemie Int. Ed. Eng. 1997, 36, 1531-1532.